Sony’s PlayStation brand had accumulated approximately 38.57 million fans on the social network

Statista
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Technology brands with the most Facebook fans as of April 2018 (in millions)

Number of fans in millions
Facebook 208.14
Facebook for Every Phone 208.14
Samsung Mobile USA 156.25
Instagram 54.31
Microsoft Windows 47.15
Netflix 44.57
Samsung Mobile 43.48
Intel 38.88
PlayStation 38.57
iTunes 30.46